The Electronic and Advanced Materials Conference (EAM) is geared towards engineers, technologists, researchers and students with an interest in science, engineering and the applications of electroceramic materials. Several MSE students and faculty attended this year’s EAM Conference held in Orlando, FL.
MSE Associate Professor and Director for Undergraduate Studies, Serge Nakhmanson, co-organized a symposium at this event entitled “Mesoscale Phenomena in Ceramic Materials.” Four UConn students including Tulsi Patel, Krishna Chaitanya Pitike, Lukasz Kuna and Hope Whitlock showcased their research.
In addition to the oral presentations, two UConn students claimed 2nd and 3rd place in the American Ceramics Society (ACerS) Electronics Division “Best Student Poster Presentation” awards. Lukasz Kuna received 3rd place for his poster entitled, “Mesoscale Simulations of the Influence of Elastic Strains on the Optical Properties of Semiconducting Core-Shell Nanowires.” Krishna Chaitayna Pitike won 2nd place for his poster, “Shape and Size Dependent Phase Transformations and Field-induced Behavior in Ferroelectric Nanoparticles.”
In response to the latter award Serge Nakhmanson said, “This remarkable work involves contributions from five UConn students (including Physics undergraduate Hope Whitelock) and an exchange student from China visiting my group. It started as a team project in the “Phase Transformations in Solids” graduate class (MSE 5305). Since the original results appeared to be significant, we decided to continue this project beyond the end of the semester to generate a publication for a peer-review scientific journal. This is now being finalized for submission. It is relatively rare to see classroom projects successfully transition into publication quality research, but this one is being well received by the community.” Department Head Bryan Huey adds, “Devising a class project that can be guided through to a publication is a testament to Professor Nakhmanson’s commitment to teaching and the hard work he inspires with these bright students.”
EAM, jointly arranged by the Electronics Division and Basic Science Division of the ACerS, focuses on the properties and processing of ceramic and electroceramic materials and their applications in electronic, electro/mechanical, dielectric, magnetic, and optical components and devices and systems.
Categories: awards, conferences, news, research, students
Whoever said rules were made to be broken wasn’t a physicist. When something doesn’t act the way you think it should, either the rules are wrong, or there’s new physics to be discovered. Which is exactly what UConn’s Connor Occhialini ’18 (CLAS), an honors student majoring in physics and math, found when he began researching scandium fluoride.
Scandium fluoride is a transparent crystal with a cubic shape, a byproduct of mining. It’s not used commercially and it wouldn’t be particularly interesting to anyone except for one odd thing: it shrinks as it warms.
Most materials swell as they heat up. Really simple materials like hydrogen gas swell because the heat makes their atoms zoom around faster, bumping into each other more, so the same number of hydrogen atoms need more space. More complicated materials also swell, which is why your wooden front door tends to stick in the summertime. But solids like wood can’t swell as much as a gas because their atoms are tightly linked together into long, interlocked molecules, so they just jiggle around, swelling the door a little bit.
Scandium fluoride must be doing something else, reasoned Occhialini. His advisor for his honors physics project, Jason Hancock, had been working with scandium fluoride, and asked Occhialini to study a model of the crystal’s dynamics. Scandium fluoride has a pretty simple structure: it’s a solid crystal, with each scandium atom surrounded by six fluorines to make stacks of octahedra (eight-sided diamonds). The researchers hoped the simple structure might be easy to understand. Understanding scandium fluoride’s strange ‘negative thermal expansion’, as physicists call the heat-related shrinkage, might yield more general insight into other, more complex materials that do the same thing.
Occhialini’s first step was to simplify the problem. So instead of a three-dimensional crystal, he decided to think about it as a two-dimensional sheet that looks like this:
Each black diamond represents a molecule of scandium fluoride. The scandium atoms (blue dots) are at the center of each diamond, and a fluorine atom is at each corner.
Most of the time, bonds between atoms are flexible. So in a normal crystalline solid – calcium fluoride, for example – the fluorines and calcium atoms would all be able to wiggle around independently when the material warmed up. As they wiggled, they’d take up a little more space, and the solid would swell. Normal solid behavior.
But Occhialini wondered if maybe that wasn’t what was happening in scandium fluoride. Maybe in this model, he should assume the bonds connecting each fluorine to its scandium were stiff? So stiff the fluorine-scandium bonds don’t move at all, so the diamonds are like solid blocks. The only places the structure would be able to flex when it warmed up would be at the fluorine atoms, which would act like tiny little joints. As the crystal heated up, the little scandium fluoride blocks would tilt around the fluorines at the corners. That’s what you see happening in the picture. You’ll notice that when the diamonds tilt, the whole structure gets smaller. It actually tightens up. The blue outline shows the structure at its coldest, perfectly ordered state, with no molecular motion. When the diamonds tilt, they take up a smaller total volume than the blue outline delineates. This is negative thermal expansion.
Occhialini figured out that you can describe this shrinkage mathematically, using just the angle of the molecules’ tilt. He called the angle Θ (theta). When the scandium fluoride blocks tilt by an angle Θ, the distance between the center of each block shortens by a factor of cosine Θ, and the crystal’s total volume shrinks.
To calculate that shrinkage (or, in a normal material, expansion) in detail, Occhialini added a third term to the classic equation that describes the energy of a vibrating crystal. The first two terms in the standard equation describe the potential energy a crystal has from the bending at each molecular junction, plus the kinetic energy of rotation of each molecule. Occhialini’s equation also describes the translational kinetic energy of the molecules–not just from rotating around, but also moving toward and away from their original positions as they rotate. The further they are from the center of mass of the crystal, the more they move. Look back at Figure 1 and notice the dot in the middle; that’s the center of mass. The diamonds in the middle barely move in relation to it, while the diamonds at the edges move a lot. Now imagine how much of a difference there would be if the crystal had millions of molecules instead of just 25. And now you understand how important that third term could be to the energy of the crystal.
Now, molecules being molecules, they don’t just shrink and stay there. They’re moving constantly, and the warmer they get, the more they move. Part of Occhialini’s insight is that, on average, the molecular structure gets bendier the warmer it gets. So the molecules tilt more and spend more time at bigger values of Θ, closer to 45 degrees. After Occhialini thought it over for a while together with Hancock and physics Ph.D. students Sahan Handunkanda and Erin Curry, they realized there was a geometric shape that had the same mathematical description. It’s Archimedes’ spiral pendulum, and it looks like this:
Each turning of the spiral is exactly the same distance from the last. That spacing – the distance between turns – is controlled by Θ. Imagine a line that stretches from the center of the sphere to a point on the spiral. The angle between that line and the pole of the sphere is Θ. You see the little ball traveling along the spiral? That’s the end of the imaginary line. As Θ gets bigger, the ball moves towards the equator.Imagine that the ball represents the instantaneous state of the scandium fluoride crystal – the physicists calculated the statistical average of what every molecule in the crystal is doing. You’ll notice the ball spends more time near the equator of the spiral sphere, that is, it tends to hang out where Θ is large. If the temperature of the crystal drops and the molecules wiggle less, Θ gets smaller, the more time the ball spends near the pole of the sphere and the less the crystal shrinks.
So not only can a really weird phenomenon of a crystal that shrinks as it warms be explained by just assuming the molecules are rigid, but it can be illustrated with a classical geometric shape!
Occhialini was just a freshman when Hancock introduced him to the scandium fluoride puzzle. He had to learn the math as he went, but after about two semesters of working on it he’d figured out the equation that described what was going on. Now in his senior year, he says his research experiences in Hancock’s lab have been integral to his experience as an undergraduate.
The equation works beautifully and explains certain aspects of Hancock’s experimental x-ray measurements as well.
“I learned a lot more doing research than any course could have given me,” Occhialini says.
And now you, dear reader, have learned a little bit, too.
John Mangeri (left) with his SCGSR-award host Dr. Olle Heinonen (right) in front of the Chemistry building (bldg. 200) at Argonne National Laboratory.
(Photo credit to Dr. Andrea Jokisaari)
By Katherine Eastman
John Mangeri, a Ph.D. candidate in Dr. Serge Nakhmanson’s “Complex Materials by Computational Design” group, was selected to receive the U.S. Department of Energy’s Office of Science Graduate Research (DoE SCGSR) award for his project, Computational Design of Functional Materials for Electrothermal Energy Interconversion on Mesoscale.
This award allowed John to conduct research on his project at the Argonne National Laboratory in Lemont, IL, for from June to September in 2016 under the guidance of the DoE collaborator, Dr. Olle G. Heinonen.
The U.S. Department of Energy states that the “SCGSR program provides supplemental awards to outstanding U.S. graduate students to pursue part of their graduate thesis research at a DoE laboratory in areas that address specific challenges central to the Office of Science mission.”
Argonne National Laboratory is one of the U.S. Department of Energy’s premier national laboratories for scientific and engineering research. Its state-of-the-art, high-performance computing facilities that were available to John during his visit enabled him to achieve rapid progress in advancing his Ph.D. project.
“I am extremely pleased with John’s research accomplishments on the way to his Ph.D. degree. John is currently the main code developer for the mesoscale-level multiphysics simulation package, ‘Ferret,’ that is being utilized by the group together with our Argonne collaborators to design new materials that can convert thermal energy into electrical and vice versa,” Dr. Nakhmanson commented.
John’s research on a new material concept for this energy conversion by utilizing an electrocaloric effect that changes the temperature of a dielectric when subjected to an external electric field was recently published in a new journal, NPJ Computational Materials, that is partnered with the prestigious scientific journal Nature. The article, entitled “Amplitudon and phason modes of electrocaloric energy interconversion,” was co-authored by John, Krishna Pitike (also a graduate student in Dr. Nakhmanson’s group), Dr. Pamir Alpay, and Dr. Nakhmanson.
In that project, the co-authors conducted a theoretical investigation of a model system made up of thin perovskite-oxide crystal layers, whose polarization directions can be easily reoriented by an applied electric field.
This unusual system, the team demonstrated, must exhibit two different kinds of electrocaloric responses, conventional and anomalous one, that can either heat the material up or cool it down with a capability to switch between these two modes on demand. Possible applications for this effect are new, integrated cooling sources for computer chips and other electronic circuits, as well as more efficient and silent HVAC devices.
“The effect we saw was quite unexpected. We were able to show that there are two kinds of energy conversion modes in that material — stemming, respectively, from either amplitudon or phason excitations of the local polar dipoles,” John said.
Even though this material does not yet exist, he further explained, quantum mechanics suggests that it could be put together by one of atomic layer-by-layer deposition techniques that are utilized for growing thin oxide films on substrates.
“It’s a good opportunity for me,” John said in reflection of his SCGSR-sponsored research experience at Argonne. “There’s always more work to do — you always have to be looking at the next step in developing your career and being exposed to a different setting for doing science really helps with evaluating your priorities.”
Dr. Ilya Sochnikov has just started new scanning SQUID microscopy lab at the University of Connecticut.
Ilya Sochnikov’s research focuses on nanoscale quantum phenomena in new materials. An emergence of a new phenomenon or a phase transition occurs when interactions in the materials are tuned via chemical, mechanical, or electromagnetic knobs. The material systems of an immediate interest include topological insulators, superconductors, and frustrated magnets. His main research tool will be a state of the art microscope for imaging of tiny magnetic fields at ultra-low temperatures and short timescales. One of the research motivations is to impact our understanding of materials properties that could provide new options for energy efficient technologies.
Jason Hancock, Assistant Professor in Physics, with graduate students, Erin Curry and Sahan Handunkanda, have been investigating a substance that shrinks when it warms.
Most materials swell when they warm, and shrink when they cool. But UConn physicist Jason Hancock has been investigating a substance that responds in reverse: it shrinks when it warms.
Although thermal expansion, and the cracking and warping that often result, are an everyday occurrence – in buildings, bridges, electronics, and almost anything else exposed to wide temperature swings – physicists have trouble explaining why solids behave that way.
Research by Hancock and his colleagues into scandium trifluoride, a material that has negative thermal expansion, recently published in Physical Review B, may lead to a better understanding of why materials change volume with temperature at all, with potential applications such as more durable electronics. For the complete article in UConn Today that explains their findings, see “Caution: Shrinks When Warm” .
Researchers have made an experimental breakthrough in explaining a rare property of an exotic magnetic material, potentially opening a path to a host of new technologies. From information storage to magnetic refrigeration, many of tomorrow’s most promising innovations rely on sophisticated magnetic materials, and this discovery opens the door to harnessing the physics that governs those materials.
The work, led by University of Connecticut professor Jason Hancock, and Ignace Jarrige of the Brookhaven National Laboratory, marks a major advance in the search for practical materials that will enable several types of next-generation technology. A paper describing the team’s results is published this week in the journal Physical Review Letters.