Month: February 2019

2 for the price of 1: UConn researcher finds new mechanism making double ionization an efficient process

Schematic of dICD

An international research team headed by Dr. Aaron LaForge from the research group of Prof. Nora Berrah in the Physics department at UConn has recently discovered a new type of decay mechanism leading to highly efficient double ionization in weakly-bound systems. The team has published its results in the science journal “Nature Physics”.

Ionization is a fundamental process where energetic photons or particles strip an electron from an atom or molecule. Normally, a much weaker process is double ionization, where two electrons are simultaneously emitted, since it requires higher-order interactions such as electron correlation. However, these new results show that double ionization doesn’t necessarily need to be a minor effect and can even be the primary ionization mechanism thereby getting two electrons for the price of one.

The enhancement is likely due to double ionization proceeding through a new type of energy transfer process termed double intermolecular Coulombic decay, or dICD, for short. The experiments were performed at the synchrotron, Elettra, in Trieste, Italy. There, electrons are accelerated to near the speed of light and then rapidly undulated through an alternating magnet field. In this way, the electrons emit short wavelength light which is needed to trigger dICD. The researchers produced superfluid helium droplets, which are cryogenic, nanometer-sized matrices capable of attaching various atomic and molecular species in order to perform precise spectroscopic measurements. In this case, dimers consisting of two alkali metal atoms were attached to the surface of helium droplets. The dICD process, schematically shown in Fig. 1, occurs through an electronically excited helium atom (red), produced by the synchrotron radiation, interacting with the neighboring alkali dimer (blue and white) resulting in energy transfer and double ionization. Although an alkali dimer attached to a helium nanodroplet is a model case, dICD is potentially relevant for any system where it is energetically allowed.

dICD belongs to a special class of decay mechanisms where energy is exchanged between neighboring atoms or molecules leading to enhanced ionization rates. Seemingly ubiquitous in weakly-bound, condensed phase systems such as van der Waals clusters or hydrogen-bonded networks like water, these processes can contribute to radiation damage of biological systems by producing particularly harmful low-energy electrons. dICD could strongly enhance such effects through the production of two low-energy electrons for each intermolecular decay.

Original publication:

A. C. LaForge, M. Shcherbinin, F. Stienkemeier, R. Richter, R. Moshammer, T. Pfeifer & M. Mudrich, “Highly efficient double ionization of mixed alkali dimers by intermolecular Coulombic decay”, Nature Physics (2019) DOI: 10.1038/s41567-018-0376-5

Kate Whitaker wins the Sloan Fellowship!

Original UConn Today article here

Rising Star in Astrophysics Receives Sloan Foundation Fellowship

Kate Whitaker, assistant professor of physics, stands next to a telescope inside the observatory on top of the Gant Complex on Feb. 14, 2019. (Peter Morenus/UConn Photo)
Kate Whitaker, assistant professor of physics, stands next to a telescope inside the observatory on top of the Gant Complex on Feb. 14, 2019. (Peter Morenus/UConn Photo)

As an assistant professor of astrophysics, Kate Whitaker spends a lot of her time thinking about stars. Hundreds of billions of stars that comprise galaxies, to be more precise. But with a recent fellowship from the Alfred P. Sloan Foundation, it is Whitaker’s star that is shining brightly.

Whitaker is one of 126 outstanding U.S. and Canadian researchers selected by the Alfred P. Sloan Foundation to receive 2019 Sloan Research Fellowships. The fellowships, awarded yearly since 1955, honor early-career scholars whose achievements mark them as among the most promising researchers in their fields.

Valued not only for their prestige, Sloan Research Fellowships are a highly flexible source of research support. Funds may be spent in any way a Fellow deems will best advance his or her work.

“Sloan Research Fellows are the best young scientists working today,” says Adam F. Falk, president of the Alfred P. Sloan Foundation. “Sloan Fellows stand out for their creativity, for their hard work, for the importance of the issues they tackle, and the energy and innovation with which they tackle them. To be a Sloan Fellow is to be in the vanguard of twenty-first century science.”

According to colleagues, Whitaker certainly fits the bill as one of the brightest young minds at UConn and beyond.

“Kate’s record so far is truly impressive and speaks to her potential as a leader in her field,” explains Barry Wells, head of UConn’s Department of Physics. “It was my great pleasure to nominate her for a Sloan Foundation Research Fellowship, and I am thrilled they felt she was worthy of the prize.”

An observational extragalactic astronomer, Whitaker’s research tries to reveal how galaxies are evolving from the earliest times to the present day.

In addition to her position at UConn, Whitaker is also an associate faculty at the new Cosmic Dawn Center in Copenhagen, Denmark. Whitaker and her students actively collaborate with DAWN, working towards pushing our detection of quiescent “red and dead” galaxies even earlier in time.

She will be among the world’s first scientists to explore the universe using the new James Webb Space Telescope when it is launched in 2019, which she says will allow her to push into new frontiers of research.

Apart from that exciting work, Whitaker and colleagues Cara Battersby and Jonathan Trump were tasked with building a full-fledged astronomy program from scratch at UConn. Not only has their work exceeded expectations, the fruits of their labor are already beginning to emerge. Whitaker and colleagues have so far created five new astrophysics courses with two more slated for next year, established an official astronomy minor, and are operating a thriving research program that involves doctoral students, undergrads, and even local high school students.

“I am both thrilled at this opportunity and humbled to be named amongst such a prestigious cohort of scientists,” says Whitaker. “With the Sloan Foundation’s generous support, I aspire to continue to lead ground-breaking studies of the distant universe, the mystery of which will no doubt captivate our imaginations.”

The Alfred P. Sloan Foundation is a philanthropic, not-for-profit grant making institution based in New York City. Established in 1934 by Alfred Pritchard Sloan Jr., then-President and Chief Executive Officer of the General Motors Corporation, the Foundation makes grants in support of original research and education in science, technology, engineering, mathematics, and economics. A full list of the 2019 Fellows is available at the Sloan Foundation website at