Prof. Emeritus Winthrop Smith and former student Prof. Douglas Goodman (Quinnipiac University) Edit Special Issue of Open Access Journal Atoms, on Low Energy Interactions between Ions and Ultracold Atoms The Special Issue of the online journal Atoms is a collection of current peer-reviewed articles by experts in the field of ultracold collisions and reactions involving […]
The Physics Department welcomes our newest faculty member, Dr. Anh-Thu Le, although he prefers to be called simply AT. AT worked for many years at the well-known James R. Macdonald Laboratory, rising to the rank of Research Professor. He worked alongside a world-known theorist, Dr. Chii-Dong Lin. Dr. Le went on to become an Assistant […]
Professor of Physics Nora Berrah has been awarded the International Blaise Pascal Chaire d’Excellence, a prestigious honor whose previous winners include scientists and scholars from a wide range of disciplines, including multiple Nobel laureates. Her award was selected by a committee of scientists and voted on by the Permanent Commission Regional Council of the Région […]
A single x-ray can unravel an enormous molecule, physicists report in the March 17 issue of Physical Review Letters. Their findings could lead to safer medical imaging and a more nuanced understanding of the electronics of heavy metals. Medical imaging techniques such as MRIs use heavy metals from the bottom of the periodic table as …
Daniel McCarron, assistant professor of physics, the College of Liberal Arts and Sciences, will receive $645,000 over five years for his work on the development of techniques to trap large groups of molecules and cool them to temperatures near absolute zero. The possible control of molecules at this low temperature provides access to new research applications, such as quantum computers that can leverage the laws of quantum mechanics to outperform classical computers.
When Carlos Trallero started his academic career in physics, he had no idea he would become a pioneer in a field of research that uses high-power lasers to investigate atomic and molecular physical phenomena. Originally from Cuba, where there isn’t much funding for experimental research, Trallero began his academic career by studying theoretical physics. But as a senior graduate student at Stony Brook University, he got the chance to work in a lab doing experimental work and quickly recognized it was his true passion.
On April 11th and 12 of 2019 Prof. Paul Corkum of the Joint Attosecond Laboratory (University of Ottawa and the National Research Council of Canada) visited the department. Prof. Corkum’s main area of research is on the interaction of ultrashort laser pulses with matter broadly defined. His most notable contribution is perhaps the discovery of […]
An international research team headed by Dr. Aaron LaForge from the research group of Prof. Nora Berrah in the Physics department at UConn has recently discovered a new type of decay mechanism leading to highly efficient double ionization in weakly-bound systems. The team has published its results in the science journal “Nature Physics”. Ionization is […]
Physics professor Nora Berrah has been named a 2018 Fellow of the American Association for the Advancement of Science (AAAS). Prof. Berrah has been recognized for her distinguished contributions to the field of molecular dynamics, particularly for pioneering non-linear science using x-ray lasers and spectroscopy using synchrotron light sources. View full story on CLAS website.
Professor Carlos Trallero has been granted $1.06 million from the Department of Defense, the U.S. Air Force and the Air Force Office of Scientific Research to study recollision physics at the nanoscale to help develop ultrafast electronics. This research will enhance the knowledge base of electron recollision dynamics at the nanoscale, which can be used to develop ultrafast light-driven electronics.
December 19, 2017 – Colin Poitras – UConn Communications Scientists from three major research universities successfully manipulated the outcome of a chemical reaction and, in doing so, created a rare molecular ion. Through a process known as “controlling chemistry,” the researchers bonded an oxygen atom to two different metal atoms, creating the barium-oxygen-calcium molecular ion or BaOCa+ The same […]
As a research assistant in the physics department at UCONN, I assisted in the alignment, maintenance, and principles of operation of the various apparatuses and measurement techniques used within cold atomic, molecular, and optical (AMO) experimental physics research. This included optical components, laser alignment, laser locking, saturation absorption spectroscopy, and electrodynamic ion trapping. Some specific […]
Cortex Fusion Systems, Inc. uses shaped ultrafast laser pulses to catalyze fusion reactions in molecules. Our work comprises (1) designing transiently confining effective one-electron potentials in field-dressed molecules, (2) performing quantum chemistry calculations to validate the enhancement of nuclear tunneling by laser-modified electron screening dynamics, and (3) testing pulse shapes in the laser lab by coupling ultrafast spectroscopy techniques with nuclear radiation detection and spectrometry. In this regard, “quantum-controlled fusion” is a coherent, under-the-barrier process that does not require plasma ignition. Our goal is to repurpose the modern suite of commercial femtosecond laser amplifiers and pulse-shaping techniques to achieve compact and scalable fusion generators using quantum control.
Dr. Esteban Goetz, Department of Physics, University of Connecticut
Interferometric Harmonic Spectroscopy for Electron Dynamics Imaging and Attosecond Pulse Train Phase Characterization
The advent of ultrashort light pulses has opened the possibility of investigating atomic and molecular processes on their natural time scales. In particular, Attosecond Transient Absorption Spectroscopy (ATAS) [1], a technique that allows to time-resolve the quantum dynamics of electrons by monitoring the absorption of extreme ultraviolet (XUV) radiation by an atomic or molecular system when the latter is dressed by an infrared (IR) laser source.
Motivated by recent experimental advances in self-referenced interferometric harmonic spectroscopy [2], we theoretically investigate an alternative approach to ATAS for electron dynamics imaging and attosecond pulse train (APT) phase characterization. In contrast to ATAS, which gives access to the imaginary part of the refractive index through an absorption measurement, an interferometric phase measurement gives information of its real part. In this talk, I will discuss the link between the XUV phase measurements of Ref. [2] and the different photoexcitation pathways occurring at the atomic level which are imprinted in the real part of the macroscopic refractive index. As an application, we show how such an interferometric approach can be used for phase retrieval of attosecond pulse trains based on two-arm harmonic spectroscopy and an optimization algorithm. Finally, I will highlight the impact of spin-orbit couplings and macroscopic and field propagation effects on the phase measurements and APT phase retrieval. Our theoretical description is based on numerical solution of the scalar Maxwell equations beyond Beer’s Law for the macroscopic field propagation coupled to the time-dependent Schroedinger equation for the quantum dynamics.
[1] M. Holler et al., Phys. Rev. Lett. 106, 123601 (2011)
[2] G. R. Harrison et al., arXiv:2305.17263 (2023)
Graduate student Geoff Harrison, Department of Physics, University of Connecticut
ITAS: A Technique for Complete Quantum Measurements on a New Timescale
Transient absorption spectroscopy is a well-established technique used to study electron dynamics in atomic and molecular systems but typically can only measure the magnitude of the electronic wavefunction. We have integrated interferometric methods into this technique to allow complete quantum measurements of both the magnitude and phase of electronic wavefunctions. A spatial light modulator (SLM) is used to separate the interferometric arms in an extremely stable way, enabling the measurement of effects on the zeptosecond timescale (with a jitter of 3zs). In this talk, I’ll describe how we’ve utilized SLMs to make these measurements possible and share some initial data we’ve taken looking at phase effects in argon.
Graduate student Debadarshini Mishra, Department of Physics, University of Connecticut
Imaging ultrafast dynamics in molecular systems
Imaging electronic and molecular dynamics at the attosecond and femtosecond timescales is crucial for understanding the mechanisms of chemical reactions, a fundamental aspect in fields ranging from materials science to biochemistry. This in-depth understanding of chemical processes may allow for precise control over reaction dynamics, thereby paving the way for advancements in technology and medicine, for example, by guiding the development of efficient catalysis, innovative materials, and targeted drugs. In this talk, I will describe our work on imaging time-resolved molecular dynamics using two distinct and complementary techniques.
In the first part of my talk, I will discuss the use of coincident Coulomb explosion imaging for the direct visualization of roaming reactions. These reactions represent unconventional pathways that allow fragments to remain weakly bonded, leading to the formation of unexpected final products. Typically, the neutral character of the roaming fragment and its indeterminate trajectory make direct experimental identification challenging. However, I will demonstrate that by leveraging the power of coincidence imaging, we can reconstruct the momentum vector of the neutral roamer and thus identify an unambiguous signature for roaming.
In the second part of my talk, I will discuss the imaging of UV-induced ring-opening and dissociation dynamics using ultrafast electron diffraction. I will demonstrate that by harnessing the superior temporal and structural resolution of this technique, we can explore the competition among different molecular pathways as well as their wavelength-dependent behavior.
Dr. François Légaré, Institut national de la recherche scientifique, Energy Materials Télécommunications center
Ultrafast IR/mid-IR laser technologies and their applications at ALLS
The Advanced Laser Light Source (ALLS) is a unique user facility located at INRS-EMT (Varennes, Canada) counting on 40M CDN$ of investment since 2002. Since 2019, this facility has jointed the LaserNetUS network and is now funded as a national research infrastructure by the Canada Foundation for Innovation – Major Science Initiatives. These fundings ease access to the facility for academic and government users. In the first part of my talk, I will give an overview of the facility’s capabilities including the most powerful laser in Canada with 750 TW. In the second part, I will discuss novel approaches developed by my team for the generation of ultrashort pulses in the IR and mid-IR spectral range. This includes multidimensional solitary states in hollow core fibers [1,2] as well as using the frequency domain optical parametric amplification for the generation of tunable CEP stable mid-IR laser pulses [3,4]. Pulse characterization in the mid-IR spectral range will be presented [5]. Finally, I will present recent results on the generation of high-dose MeV electrons from tight focussing in air [6].
References
[1] R. Safaei, G. Fan, O. Kwon, K. Légaré, P. Lassonde, B. E. Schmidt, H. Ibrahim, and F. Légaré (2020), High-energy multidimensional solitary states in hollow core fiber, Nature Phot. 14, 733-739.
[2] L. Arias, A. Longa, G. Jargot, A. Pomerleau, P. Lassonde, G. Fan, R. Safaei, P. Corkum, F. Boschini, H. Ibrahim, and F. Légaré, Few-cycle Yb laser source at 20 kHz using multidimensional solitary states in hollow-core fibers, Opt. Lett. 47, 3612-3615 (2022).
[3] A. Leblanc, G. Dalla-Barba, P. Lassonde, A. Laramée, B. Schmidt, E. Cormier, H. Ibrahim, and F. Légaré (2020), High-field mid-infrared pulses derived from frequency domain optical parametric amplification, Opt. Lett. 45, 2267-2270.
[4] G. Dalla-Barba, G. Jargot, P. Lassonde, S. Tóth, E. Haddad, F. Boschini, J. Delagnes, A. Leblanc, H. Ibrahim, E. Cormier, and F. Légaré, Mid-infrared frequency domain optical parametric amplifier, Opt. Express 31, 14954-14964 (2023).
[5] A. Leblanc, P. Lassonde, S. Petit, J.-C. Delagnes, E. Haddad, G. Ernotte, M. R. Bionta, V. Gruson, B. E. Schmidt, H. Ibrahim, E. Cormier, and F. Légaré (2019), Phase-matching-free pulse retrieval based on transient absorption in solids, Opt. Express 27, 28998.
[6] S. Vallières, J. Powell, T. Connell, M. Evans, M. Lytova, F. Fillion-Gourdeau, S. Fourmaux, S. Payeur, P. Lassonde, S. MacLean, and F. Légaré, High Dose-Rate MeV Electron Beam from a Tightly-Focused Femtosecond IR Laser in Ambient Air (2024), Laser Photonics Rev. 18, 2300078.
François Légaré is a chemical physicist who specializes in developing novel approaches for ultrafast science and technologies, as well as biomedical imaging with nonlinear optics (Ph.D. in chemistry, 2004 – co-supervised by Profs. André D. Bandrauk and Paul B. Corkum). Full professor (2013 - …) at the Energy Materials Telecommunications center of the Institut national de la recherche scientifique (INRS-EMT), he was the director of the Advanced Laser Light Source (ALLS) until 2023. Since 2022, he is the director of the INRS-EMT center and CEO of ALLS. Under his scientific leadership, INRS has received in 2017 a grant of 13.9M CDN$ from the Canada Foundation for Innovation and the Quebec government, with 11.9M CDN$ to upscale the ALLS facility with high average power Ytterbium laser systems and advanced instrumentation for time-resolved material characterization. He is a Fellow and senior member of OPTICA and Fellow of the American Physical Society. He is a member of The College of New Scholars, Artists and Scientists of the Royal Society of Canada (2017). He was awarded the Herzberg medal from the Canadian Association of Physics in 2015 and the Rutherford Memorial Medal in physics of the Royal Society of Canada in 2016. He has contributed to about 200 articles in peer reviewed journals including prestigious ones such as Nature, Science, Nature Photonics, Nature Physics, Nature Communications, and Physical Review Letters. According to Google Scholar, his h-index is 59 with more than 13,000 citations.
I will discuss experiments and calculations that demonstrate long lived electronic coherences in molecules using a combination of measurements with shaped octave spanning ultrafast laser pulses, 3D velocity map imaging and calculations of the light matter interaction. Our pump-probe measurements prepare and interrogate entangled nuclear-electronic wave packets whose electronic phase remains well defined despite vibrational motion along many degrees of freedom. The experiments and calculations illustrate how coherences between excited electronic states survive even when coherence with the ground state is lost, and may have important implications for light harvesting, electronic transport and attosecond science.
The continuously improving performance of quantum sensors is enabling the exploration of fundamental physics with unprecedented precision. Notable examples of these systems include optical atomic clocks and atom interferometers, which are among the most precise devices ever invented by humankind. As a result, they are increasingly utilized in the search for new physics. The application of Atomic, Molecular, and Optical (AMO) Physics techniques to such inquiries in the realm of nuclear physics has been gaining attention in the current decade. The level of control and precision achievable in AMO tabletop experiments, especially with ultracold atoms, enhances the measurement capabilities in complex experimental systems that pursue tests of fundamental physics and symmetries, the search for the electron electric dipole moment (eEDM), and physics beyond the standard model. In this talk, I will explain how incorporating entanglement into these systems can further improve their measurement capabilities. Additionally, I will discuss several proposals that employ laser-cooled atoms and molecules in the search for physics beyond the Standard Model.
Post-Nobel Award on attosecond Science – Challenges and opportunities in the field going forward
It is an exciting month for the attosecond and strong-field physics communities after the announcement of the three Nobel Laureates earlier. How will this field evolve going forward? While it is very attractive to talk about the shortest light pulses to the general public, and even to the physical science community, the field still faces great challenges but also opportunities. I will “talk” about the challenges and will share with you some of the recent progress toward developing theories that can be compared to experiments.
Dr. Sandra Beauvarlet, UConn and PULSE, SLAC National Laboratory
Attosecond X-ray pulse pair generation at SLAC- LCLS X-ray Free Electron Laser and application to probe ultrafast electron dynamics in aminophenol
I will present in this AMO seminar general notions about how Free Electron Laser (FEL) work and will present some of the characteristics and more recent developments at the SLAC X-ray FEL light source. I will discuss the key advances to reach the sub-fs timescale enabling the production of isolated attosecond X-ray pulses but also the generation of attosecond X-ray pulse pairs with controllable delays. These pulses open the way to pump-probe measurements of ultrafast dynamics with attosecond temporal resolution and angstrom spatial resolution due to the X-ray nature of the light produced. Going from a more technical development perspective to an experimentalist vision, I will report on two examples of attosecond X-ray pump - attosecond X-ray probe measurements conducted on gas phase Aminophenol molecules (C 6 H 7 NO). The first one relies on carbon K-shell ionization and the effect of post-collision interaction (PCI). The second one relies on X-ray absorption spectroscopy to probe charge migration across the molecules on a sub-10 fs timescale.